This type of attack results from local differences in composition, such as coring commonly encountered in alloy castings. This article presents the results of an investigation that combines standard methods of fracture mechanics, empirical correlations of stress corrosion cracking, and probabilistic methods to provide an assessment of intergranular stress corrosion cracking igscc of stainless steel piping. Intergranular stress corrosion cracking scc of pipelines has been known to cause. Intergranular stress corrosion cracking igscc of austenitic stainless steels, usually aisi 304 steel, is a serious problem in boiling water reactors bwr. In nickel alloys and austenitic stainless steels, where chromium is added for corrosion resistance, the mechanism involved. Intergranular stress corrosion cracking initiation model of austenite. Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions, and high temperature. A specific objective of this work was to predict the performance of alloy casting institute cf3, cf3a, and cf8 castings in nuclear applications. Effects of hydrogen peroxide on intergranular stress.
Stress corrosion cracking of an austenitic stainless steel in. What is intergranular stress corrosion cracking igscc. Intergranular stress corrosion cracking igscc is stress corrosion cracking where the grain boundaries of a susceptible material are cracked due to stress and an agressive environment. How to reduce the risk of stress corrosion cracking scc the risk of stress corrosion cracking. Effects of dissolved hydrogen and strain rate on iascc. It is thought to start with chromium carbide deposits along grain boundaries that leave the metal open to corrosion. Sensitization refers to the precipitation of carbides at grain boundaries in a stainless steel or alloy, causing the steel or alloy to be. Iascc behavior in coldworked sus316 stainless steels irradiated to 35 dpa was examined using slow strain rate tensile testing at a strain rate of 6. Cracks initiated at intergranular corrosion penetrations propagating by corrosion assisted.
Intergranular attack in welded stress corrosion resistant stainless steels satisfactory stress corrosion resistance is obtained using arc welding and, depending on the base metal, type 376. Intergranular stress corrosion cracking in rbmk reactors to assist countries operating rbmk reactors in addressing the issue in austenitic stainless steel 300 mm diameter piping. Brittleness results, causing the metal to crack near the weld. Welding stainless steel is very different than welding carbon steel, and can lead to problems such as intergranular corrosion, hot cracking and stress corrosion cracking.
Detection and characterisation of intergranular stresscorrosion cracking on austenitic stainless steel article pdf available in materials and corrosion 638. The intergranular stress corrosion cracking of sensitized 304 stainless steel in na2s2o3 solutionwas detected by electrochemical noise en. For the study, a criterion for the rate of intergranular corrosion igc for detecting the susceptibility to intergranular stress corrosion cracking igscc in hightemperature oxygenated pure water was established by quantitatively evaluating the results from a modified astm a262e test. Intergranular attack in welded stresscorrosion resistant. Pdf the influence of material factors on the intergranular stress corrosion cracking igscc susceptibility of austenitic stainless steels under. This paper evaluates the resistance to intergranular stress corrosion cracking igscc in the boiling water reactor of several grades and compositions of austenitic stainless steel castings. Grain boundary precipitation, notably chromium carbides in stainless steels, is a well recognized and accepted mechanism of intergranular corrosion. Stress corrosion cracking odonnell consulting engineers. Stress corrision cracking is a relatively rare form of corrosion, which requires a specific combination of tensile stress, temperature and corrosive species, often the chloride ion, for it to occur. This mode of attack is termed stress corrosion cracking scc.
Intergranular stress corrosion cracking scc of pipelines has been known to. There are two modes of stress corrosion cracking in austenitic stainless steels, namely intergranular and transgranular stress corrosion cracking, i. Duplex stainless steels have high resistance to localized corrosion particularly pitting, crevice corrosion, and stress corrosion cracking. Stress corrosion cracking scc is a common issue with many specialty alloys. Observations of intergranular stress corrosion cracking in a. Considering weld decay and knife line attack kla, intergranular corrosion takes place when welding operations occurs in stainless steels. The environmental and metallurgical factors in the intergranular stress corrosion cracking of austenitic stainless steel at temperatures below 100 c has been examined. Intergranular corrosion occurs in certain grades of stainless steel when the steel is heated, as in welding.
Intergranular and transgranular stress corrosion cracking of the aisi 316l stainless steel at polythionic acid environment 8. Grain boundary control for improved intergranular stress. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Scc is often associated with chlorides, but can also occur with caustics and other corrosive media. The figure on the left is the normalized microstructure and the one on the right is the sensitized structure and is susceptible to intergranular corrosion or intergranular stress corrosion cracking. Nrc position on igscc in bwr austenitic stainless steel piping generic letter 8801 intergranular stress corrosion cracking igscc. When welding austenitic stainless steels, grades such as 304l or 347 should be used. It is as a result of chromium depletion, mainly due to the precipitation of. Stress corrosion cracking international institute of. Introduction one of the most accepted mechanisms of stress corrosion cracking scc i.
The most weldable stainless steels are typically in the austenitic group. Intergranular corrosion stainless steel tubing manufacturer. In aqueous environments, metals may be exposed to not only uniform corrosion, but also to various types of local corrosion including pitting, crevice, intergranular, stress, and galvanic corrosion. Sensitization refers to the precipitation of carbides at grain boundaries in a stainless steel or alloy, causing the steel or alloy to be susceptible to intergranular corrosion or intergranular stress corrosion cracking. Stress corrosion cracking the international institute of. Sensitization, intergranular attack, stress corrosion. Most notably, pitting and cracking in this instance had initiated andor. Intergranular corrosion might occurs in steel alloys with chromium, niobium or titanium, and in aluminium alloys with cooper or magnesium. Austenitic stainless steels such as types 304 and 316 are susceptible to intergranular corrosion igc and intergranular stress corrosion cracking igscc when heat treated at temperatures in the range of 450sup 0 to 850sup 0c. On the mechanism of intergranular stress corrosion cracking of.
Failure analysis of corrosion on stainless steel fasteners. Another form known as sulphide stress corrosion cracking sscc is associated with hydrogen sulphide in oil and gas exploration and production. It results from chromium depletion in the vicinity of carbides precipitated at grain boundaries. Fracture mechanicsbased testing was used to quantify the stress corrosion cracking and corrosion fatigue behavior of a precipitationhardened martensitic stainless steel. Because the chromium is the primary alloying element that makes stainless steel corrosion resistant, the chromiumdepleted regions are susceptible to preferential corrosion attack. Supermartensitic stainless steels smss, including both lean grades without molybdenum and high grades with 2% molybdenum, have shown sensitivity to intergranular corrosion or stress corrosion cracking igscc in weld hazs during laboratory testing in chloride solutions acidified with co 2 at above about 100c. Stainless steel s rustresistant properties make it an. This causes the steel or alloy to become susceptible to intergranular corrosion or intergranular stress corrosion cracking. Pdf intergranular cracking of aisi 316ng stainless steel. Oct 23, 2014 which materials can be affected by intergranular corrosion. The mechanism of intergranular stress corrosion cracking of. The photos above show the microstructure of a type 304 stainless steel. Influence of chromium depletion on intergranular stress.
Intergranular stress corrosion cracking of welded steel twi. The mechanism for igscc of pipeline steels apix65 is based on the presence of hydroxyl ions at the steel. Igscc of bwr low carbon and stabilized stainless steels, late 1980s. Intergranular corrosion igc is a selective attack in the vicinity of the grain boundaries of a stainless steel. All licensees of operating boiling water reactors bwrs and holders of construction permits for bwrs subject. The interaction of corrosion fatigue and stresscorrosion. Cracking of stainless steel nozzle sleeve metallurgical. It is as a result of chromium depletion, mainly due to the precipitation of chromium carbides in the grain boundaries. Understanding and avoiding intergranular stress corrosion cracking of welded supermartensitic stainless steel. Nrc position on intergranular stress corrosion cracking igscc in bwr austenitic stainless steel piping generic letter 8801, supplement 1 february 4, 1992 to. Chloride stress corrosion cracking stainless steel corrosion corrosion of piping corrosion process surface coatings for corrosion corrosion resistant material bi metallic corrosion. Babout, n stevens materials performance centre, university of manchester, oxford rd, manchester, uk tel.
It is associated with the simultaneous presence of a number of factors. Inter granular corrosion can be detected by ultrasonic and eddy current methods. Intergranular corrosion of stainless steel often occurs after an incorrect heat treatment, and the heat treatment that causes the intergranular corrosion tendency of stainless steel is called. Pdf intergranular stress corrosion cracking behavior of. Chloride stress corrosion cracks were also found at the corrosion sites. Intergranular corrosion igc, also known as intergranular attack iga, is a form of corrosion. The selfhealing property of the passive film make the steel stainless. C for one hour, no intergranular corrosion was observed in tp321 and tp347 welded joints. Intergranular corrosion facts and how to reduce the risk. Intergranular stress corrosion cracking igscc is more common than transgranular scc. Jul 18, 2008 nondestructive threedimensional mapping of grain shape, crystallographic orientation, and grain boundary geometry by diffraction contrast tomography dct provides opportunities for the study of the interaction between intergranular stress corrosion cracking and microstructure. Although no stainless steel grade is totally immune to chloride scc, the relative resistance of stainless steels varies substantially. The use of a duplex stainless steel with molybdenum such as stainless alloys 2205 or 2507 would resist crevice corrosion and stress corrosion cracking.
Chloride stress corrosion cracking in austenitic stainless steel is characterized by the multibranched lightning bolt transgranular crack pattern. Intergranular stress corrosion cracking of austenitic stainless steel piping in bwrs has been a major safety concern since the early seventies. Effect of grain boundary network on the intergranular stress. Intergranular corrosion is sometimes also called intercrystalline corrosion or interdendritic corrosion. Chromium carbides can be precipitated if the stainless steel is sensitized in the temperature range 550850c. In areas where corrosion is a concern, stainless steel. Feb 06, 2011 intergranular corrosion igc microstructure of metals and alloys is made up of grains separa ted by grain boundaries intergranular corrosion is a localized attack along the grain bo undaries, or immediately adjacent to grain boundaries, while the bulk of t he grains remain largely unaffected igc is associated.
The most common environmental exposure condition responsible for scc of stainless steels is the presence of chlorides. For this reason, a postweld heat treatment is needed before reinstalling stainless steel parts. Stainless steel corrosion pitting corrosion crevice. The main form of corrosion of stainless steel corrosion surface corrosion, pitting corrosion, crevice corrosion and stress corrosion. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. Intergranular cracking proceeds along the grain boundaries whereas transgranular cracking does not have preferences for boundaries 69. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical. Postweld heat treatment to avoid stress corrosion cracking. Intergranular attack in welded stresscorrosion resistant stainless steels satisfactory stress corrosion resistance is obtained using arc welding and, depending on the base metal, type 376. Cracks initiated at intergranular corrosion penetrations propagating by corrosion assisted fatigue. Intergranular stress corrosion cracking igscc of structural materials such as type 304 stainless steel 304ss and type 316l stainless steel. Intergranular cracking is also known as intergranular corrosion, intergranular corrosion cracking, intergranular stress corrosion cracking igscc, intercrystalline corrosion, interdendritic corrosion or intergranular attack. Chloride stress corrosion cracking in austenitic stainless.
One of the most important forms of stress corrosion that concerns the nuclear industry is chloride stress corrosion. If we change the alloy, perhaps to a 6% mo stainless steel. Supermartensitic stainless steels smss, including both lean grades without molybdenum and high grades with 2% molybdenum, have shown sensitivity to intergranular corrosion or stress. Figure 4 shows the results of polythionic acid stress corrosion cracking. Stress corrosion cracking facts and how to reduce the. Pdf detection and characterisation of intergranular stress. Dec 19, 2019 intergranular cracking is a form of corrosive attack that progresses preferentially along grain boundaries. Transgranular, granulated, and intergranular stress corrosion. Ricker, national institute of standards and technology stresscorrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. Investigation on nucleation of intergranular stress corrosion. Intergranular stress corrosion cracking scc mechanism in sensitized stainless steel type 304 was investigated experimentally.
Characterization of intergranular stress corrosion cracking of 304. For this reason, a postweld heat treatment is needed before reinstalling stainless steel parts that have been welded. This study evaluates the nucleation criterion for intergranular stress corrosion cracking scc on a smooth surface of type 304 austenitic stainless steel from a mechanical viewpoint. Nrc position on igscc in bwr austenitic stainless steel. The corrosion runs from the outside top and in down and is caused by. Intergranular corrosion induced by environmental stresses is termed stress corrosion cracking. Galvanic corrosion intergranular corrosion intergranular corrosion of stainless steel tubes corrosion resistant stainless steel tube corrosion resistance of. Scc testing was conducted under a constant load, and microscopic strains on a smooth surface were measured in situ by the digital image correlation technique. The use of 316l would be more resistant to crevice corrosion attack. Dec 19, 2019 intergranular stress corrosion cracking igscc is a type of corrosion due to applied forces on the granular boundaries of a material. Grain boundary control for improved intergranular stress corrosion cracking resistance in austenitic stainless steels j marrow, d engelberg, a jivkov, p wood, l. This article presents the results of an investigation that combines standard methods of fracture mechanics, empirical correlations of stress corrosion cracking, and probabilistic methods to provide an assessment of intergranular stress corrosion cracking igscc of stainless steel.
Recognize the mechanism for igscc and the conditions that make igscc more likely. The most common type of stress corrosion cracking in stainless. Intergranular corrosion igc and intergranular stress corrosion cracking igscc of the lasermodified surface of alloy 600 containing 0. Direct correlations are made between the extent of chromium depletion at grain boundaries and intergranular stress corrosion cracking igscc of 304 stainless steel during. Some tips to avoid corrosion on your stainless steel tanks. Reliability analysis of stainless steel piping using a. Chloride stress corrosion cracking although no stainless steel grade is totally immune to chloride scc, the relative resistance of stainless steels varies substantially.
Intergranular stress corrosion cracking has occurred in bwr environments in nonsensitised, coldworked austenitic stainless steel materials. Corrosion is galvanic corrosion of metal surfaces all. It is believed that this occurs because the chromium content immediately adjacent to the carbide may be below that required for the stainless steel alloy. Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress.
The use of material susceptible to stress corrosion cracking scc a precursor of stress corrosion cracking in chloridebearing environments is pitting corrosion, occurring if the stainless steel is not sufficiently resistant to pitting. Sep 18, 2017 fracture mechanicsbased testing was used to quantify the stress corrosion cracking and corrosion fatigue behavior of a precipitationhardened martensitic stainless steel custom 465h950 in full. Different kinds of corrosion on stainless steel montanstahl. In the presence of tensile strength, cracking may occur along grain boundaries and this type of corrosion is frequently called interranular stress corrosion cracking igscc or simply intergranular corrosion cracking. Intergranular stress corrosion cracking resistance of. May 22, 2015 united states nuclear regulatory commission washington, d. Intergranular stress corrosion cracking of austenitic. Stress corrosion cracking of an austenitic stainless steel.
Intergranular attack of austenitic stainless steels with austenitic stainless steels, intergranular attack is usually the result of chromium carbide precipitation cr23c6 at grain boundaries. Gooch introduction although austenitic stainless steels. The intergranular cracks and grain boundary gb network of a gbengineered 316 stainless steel after stress corrosion cracking scc test in high temperature high pressure water of reactor. Potentiostatic slow strain rate tests ssrt were performed to investigate the susceptibility to intergranular stress corrosion cracking igscc of type 304l uns s30403 stainless steel ss in 299 c water, focusing on corrosion potential and the degree of sensitization. The behavior of annealed and sensitized microstructures in a variety of environments, including oxygencontaining pure water and aqueous solutions containing species such as. The combination of tensile stress and a specific corrosive environment can crack stainless steels. Paper presented at stainless steel world 2005 conference, maastricht, the netherlands, 810 november 2005. Austenitic stainless steels such as types 304 and 316 are susceptible to intergranular corrosion igc and intergranular stress corrosion cracking igscc when heat treated at temperatures in. Postweld heat treatment to avoid intergranular stress corrosion cracking of supermartensitic stainless steels. In the case of transgranular scc, the cracks advanced across the specific crystal planes with low indices 70.
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